OllyDbg is described as '32-bit assembler level analysing debugger. Emphasis on binary code analysis makes it particularly useful in cases where source is unavailable' and is a popular Decompiler in the development category. There are more than 10 alternatives to OllyDbg for a variety of platforms, including Windows, Linux, Mac, BSD and Haiku apps. The best OllyDbg alternative is x64dbg, which is both free and Open Source. Other great apps like OllyDbg are Ghidra, IDA, GNU Project Debugger and radare.
It's open source and has all the features you would expect, and it will work with both 64b and 32b software perfectly!