Libreboot is described as 'Free software project based on coreboot, aimed at replacing the proprietary BIOS firmware contained by most computers. Libreboot is a lightweight system designed to perform only the minimum number of tasks necessary to load and' and is a Boot Manager in the os & utilities category. There are seven alternatives to Libreboot for a variety of platforms, including Linux, Windows, Mac, BSD and Haiku apps. The best Libreboot alternative is GNU GRUB, which is both free and Open Source. Other great apps like Libreboot are coreboot, iReboot, Das U-Boot and Chimera.
GRUB is a boot loader while Libreboot is a BIOS replacement (which starts before the bootloader)